For 4), start by writing a balanced chemical equation between I
- and S
2O
82- first. Then use the mole ratio and number of moles of the limiting reagent you found in 3) to calculate the answer.
5a is easy. Just use the volume and concentration of S
2O
32- to calculate the answer.
5b you have to write a balanced equation between I
2 and S
2O
32- first.
5c not sure(I haven't learnt 'extent of reaction')
By the way, re-read the Forum Rules:
http://www.chemicalforums.com/index.php?topic=65859.0. You should show your attempts/thoughts at the problem when trying to receive help here.