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Topic: Acid-Base Reaction  (Read 2018 times)

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Offline Krashy

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Acid-Base Reaction
« on: February 01, 2017, 09:17:49 AM »
Hi guys, need help with calculating pH from this problem:

1,40 grams sodium dihydrogen phosphate (NaH2PO4) has been dissolved in 500 mL of water.
Assume in this problem that the dissolution of a solid in a liquid will not lead to an increase in the volume of that liquid.

a) Give the equations for the acid-base reactions that are possible between H2O and H2PO4-


H2O + H2PO4-     ------>  H3PO4 + OH-


b) Point out whether the described solution is acidic, basic or neutral responding.


500 g H2O x 1 mol H2O   = 27.75 mol H2O
                  18.02 g H2O

1.40 g NaH2PO4 x 1 mol NaH2PO4   = 0.012 mol NaH2PO4
                          119.98 g NaH2PO4


M = 0.012 / 0.5 L
M = 0.024

pH = -log 0.012

pH = 1.92

-> so its acidic (?)

I think this problem is not so hard, i´m probably just too stupid thanks for help  :)

Offline AWK

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Re: Acid-Base Reaction
« Reply #1 on: February 01, 2017, 09:26:41 AM »
Quote
a) Give the equations...
There are two different equations nedded for approximate pH calculation of this salt.

Problem is not so stupid - pH should be close to 4.5.
AWK

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Re: Acid-Base Reaction
« Reply #2 on: February 01, 2017, 09:37:41 AM »
Hint: google for pH of amphiprotic salt.
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