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Are these half reactions correct?
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Topic: Are these half reactions correct? (Read 3350 times)
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Lourdes
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Are these half reactions correct?
«
on:
May 16, 2017, 05:04:47 AM »
Hi!
I have another redox equation here:
Hg + HNO3 + H2SO4 → NO + Hg+ + H2O + SO42-
Did I identify the following as the correct half reactions:
Ox.: Hg → Hg+
Red.: HNO3 → NO
Now I did not balance out O-atoms or charges yet, just wanted to make sure if these are OK.
Thank you!
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Hunter2
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Re: Are these half reactions correct?
«
Reply #1 on:
May 16, 2017, 05:17:00 AM »
Mercury will go to Hg
2+
.
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Lourdes
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Re: Are these half reactions correct?
«
Reply #2 on:
May 16, 2017, 06:55:57 AM »
Oh but it says Hg+ on the product side, what am I missing?
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Hunter2
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Re: Are these half reactions correct?
«
Reply #3 on:
May 16, 2017, 07:03:50 AM »
If you google mercury-I-nitrate or -sulfate you will find that it only will be obtained in very diluted acidic solution under hydrogen development. If the nitric is more concentrated it will get Mercury-II-nitrate or sulfate, if sulfuric is also present.
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Arkcon
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Re: Are these half reactions correct?
«
Reply #4 on:
May 16, 2017, 07:40:18 AM »
Hg
+
is a special case, it usually appears as Hg
2
2+
. So you shouldn't use it as you have, unless the problem is just written that way by the instructor.
«
Last Edit: May 16, 2017, 09:20:59 PM by Arkcon
»
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Hey, I'm not judging. I just like to shoot straight. I'm a man of science.
Lourdes
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Re: Are these half reactions correct?
«
Reply #5 on:
May 16, 2017, 08:03:08 AM »
Thank you very much guys! But as you said the problem was given by the instructor in this way, so I am going to continue with Hg+. But apart from that, is the reduction OK?
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Hunter2
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Re: Are these half reactions correct?
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Reply #6 on:
May 16, 2017, 08:06:06 AM »
Reduction is ok.
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Lourdes
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Re: Are these half reactions correct?
«
Reply #7 on:
May 16, 2017, 08:57:50 AM »
Thank you very much Hunter2!
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Are these half reactions correct?