i am searching for a liquid with boiling point below 100°c
A good starting point, for solving this problem for yourself, would be to check the CRC. Once you find some chemicals with the boiling point you want, you can check other references to see if they match the other properties you need.
which is non flammable
Something you can check in references once you have a shorter list than "everything"
and could withstand heat and high pressure
You will not get useful answers without qualifying these values better. How much heat, for how long? How much pressure? Raising pressure raises boiling point, so if you raise pressure enough, you can reach a boiling point above 100 C. In which case, you can just use a cheap solvent, called water. Unless you can't for another reason. You can also give us that reason.
without oxidizing
You can prevent oxidation with antioxidant additives, or use something that doesn't oxidize. Or prevent oxygen from reaching it. Unless you mean other thermal degradation. Also, pressure may have no effect on oxidation, unless you mean pressurized air, or high temperature pressurized steam.
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