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Topic: Stump the Chump...Tough Decomposition Rxn  (Read 5242 times)

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Offline Isomer

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Stump the Chump...Tough Decomposition Rxn
« on: July 10, 2006, 05:45:35 PM »
I even have the answer to this question and I STILL don't know how to do it!!!!


Assume that an inflated air bag contains 169 L of Nitrogen gas at 25 degrees celsius and 485 kPa. What mass of sodium azide is required to produce this amount of nitrogen?

Here is the formula I figured....

2 NaN3 solid ---------> 3 N2 gas + 2 Na solid + 43.5 kJ

Info I calculated..

molar heat of formation of sodium azide is.....+ 21.8 kJ
molar mass of sodium azide is........+ 65.02
molar mass of nitrogen gas is.......+ 28.02

The formulas I've been fiddling with ( ^ means delta)

q = mc^t and ^h = n^h (formation)

I've tried anything and everything to no avail!

The answer is 1.43 kg. I think the 485 kPa is useless informatiion. And that is all I know! I am the chump who is stumped!!!


Offline skyglow1

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Re: Stump the Chump...Tough Decomposition Rxn
« Reply #1 on: July 10, 2006, 06:36:43 PM »
You need to use the equation pV=nRT to find out the number of moles of N2 first I'm pretty sure. That is where the pressure comes in.

Offline lemonoman

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Re: Stump the Chump...Tough Decomposition Rxn
« Reply #2 on: July 12, 2006, 05:19:57 PM »
Yup.  Sorry to say the two equations you were fiddling with..."q = mc^t and ^h = n^h (formation)", aren't the ones you want.

If you're wondering how to catch these kinds of questions...we look at what we're given

"169 L of Nitrogen gas" gives a volume, V
"at 25 degrees celsius" gives a temperature, T
"and 485 kPa" gives a pressure, P
"What mass of sodium azide" says we want a mass, m.  Mass is always related to the amount of something, which is a counted number...as in moles of nitrogen...# of moles is usually n

So we have V, T, P, and we need m (or n, since n is related to m)

Sounds like work for PV=nRT ... and voila!  Best of luck!

Offline skyglow1

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Re: Stump the Chump...Tough Decomposition Rxn
« Reply #3 on: July 12, 2006, 11:30:17 PM »
Remember to convert to SI units before putting your values into the pV=nRT equation :)

Offline Isomer

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Re: Stump the Chump...Tough Decomposition Rxn
« Reply #4 on: July 13, 2006, 01:45:11 AM »
Thanks. I figured it out!!

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