OK, this could fall under physics and chemistry I guess. Take the human body for starters. Pay attention to where you shift your weight when you walk, how your legs move, how joints work, and so on. Scientists have been having a tough time replicating bipedal motion in a robot, and there is a lot of balance problems. So lets take a look at another way to move a robot. Pilot it with hand and foot controls? You still have a balance issue, nor would you have fine control over joint movement as you would in your own body. Pilot it using your own body as a model!
This is basically how it will work when one of the nice members here donate a large sum of money to my "build a big walking robot" fund. Wear a nylon (or spandex) suit. Two ways you can handle this at this point. Snag a crapload of laser diodes from laser pens, or buy them in bulk. Have them spaced all over your suit. Sections of your suit will be attached to the inside of the robot. You will be riding around inside this thing, with your feet on rollers. Inside your "cockpit" you will be surrounded by photovoltaic cells. When you move, the laser diodes are of course going to be pointing somewhere else. I still have my electrical engineering book, and it shouldn't be TOO hard to build a simple IC that can look at how far apart cells are activated to figure out how much acceleration and speed your limbs are generating. Another way to do this is to build accelerometers and speedometers directly on the suit. You will be (mostly) suspended inside this thing so you will have a decent range of motion, enough to walk naturally on the rollers.
Now how is this useful? Using a variable voltage output from the processor, power is delivered (relay driven) to the electrical motors. You'll have "muscle groups" that are matched to the muscular structure of the human body. Get rid of the head and hands though, not necessary for walking. When you move a muscle group, say lift a leg, the robot will activate the same muscle group at the same time, with a corresponding amount of force. So what is a robot muscle group? 4 electric winches each with a steel cable attached. They contract only. Kill power and they "relax" to starting position. Install shocks in the lower legs to dampen walking pressure.
Power source! Old 1980's 4-cylinder truck motor that operates a series of alternators, and a fat battery pack. Put all the power stuff in the groin area for a lower center of gravity, and while you're at it make the feet BIG. Kind of like a midget softball player, only 30 feet tall. If YOU lose balance easily, so will the robot. Just don't do your simulated walk too fast, otherwise the steel cable driven muscles won't be able to keep up.
Well I guess this is more physics than chemistry after all. What would be a good battery for something like this? Think hollow steel tube would be good for a superstructure (cheap)? Any idea how much tiny accelerometers and speedometers cost? The rest I can plan for. Any ideas on motors to use?
What about those new polymers that contract when voltage is applied? Do they come in sheets? How do I make them? AND! ... just what is the chemistry behind those things anyway? They're pretty snazzy.