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Topic: Organometallic Chemistry  (Read 15442 times)

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eddieq

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Organometallic Chemistry
« on: January 04, 2005, 08:39:22 AM »
Hello i am a newbie if u could help me i'd appreciate it.
I have a homework i cant solve ... i have searched for the IUPAC nomenclature of the following organometallic compounds
1. [Co(NH3)4(H2O)Br](NO3)2
2. Na[Au(CN)2 ]
3. [Ni(CO)2(Ph3P)2 ]
4.Na3[Fe(C2O4)3 ]
 but i haven been able to get them. I have even used ChemFinderTM.
Please whatever u can do to help me , i will appreciate it.
God bless.
Eddieq
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Offline AWK

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Re:Organometallic Chemistry
« Reply #1 on: January 04, 2005, 09:48:47 AM »
« Last Edit: January 04, 2005, 09:55:10 AM by AWK »
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Offline kevins

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Re:Organometallic Chemistry
« Reply #2 on: January 04, 2005, 10:19:44 AM »
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Offline Winga

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Re:IUPAC nomenclature
« Reply #3 on: January 04, 2005, 11:06:00 AM »
1. [Co(NH3)4(H2O)Br](NO3)2
aquabromotetraamminecobalt(III) nitrate

2. Na[Au(CN)2]
sodium dicyanoargentate(I)

3. [Ni(CO)2(Ph3P)2]
dicarbonylbis(triphenylphosphine)nickel(II)

4.Na3[Fe(C2O4)3]
sodium trioxalateferrate(III)
or
sodium tris(ethanedioate)ferrate(III)
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eddieq

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Re:IUPAC nomenclature
« Reply #4 on: January 04, 2005, 12:56:53 PM »
Thank u Winga , I am so grateful  :hug2:
eddieq
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Offline AWK

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Re:Organometallic Chemistry
« Reply #5 on: January 05, 2005, 05:05:03 AM »
sodium dicyanoaurate(I)

tetraammineaquabromocobalt(III) dinitrate

dicarbonylbis(triphenylphosphine)nickel(0)

sodium trioxalatoferrate(III)  
« Last Edit: January 05, 2005, 05:44:20 AM by AWK »
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Offline Winga

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Re:Organometallic Chemistry
« Reply #6 on: January 05, 2005, 06:56:55 AM »
Thanks for correcting my mistakes! ;)

aurate or argentate?

dinitrate, should we need to mention "di"? (NO3- is not a ligand)
« Last Edit: January 05, 2005, 06:57:53 AM by Winga »
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Offline AWK

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Re:Organometallic Chemistry
« Reply #7 on: January 05, 2005, 08:36:23 AM »
2. Na[Au(CN)2 ]
Au - aurate
Ag - argentate

dinitrate - not abreviated form
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eddieq

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Re:Organometallic Chemistry
« Reply #8 on: January 06, 2005, 05:14:57 AM »
hello,
thanx for the help i got my corrections.
How about naming this its also givin me head ache ... its just a practice question i saw in a book.

attached below:
« Last Edit: January 06, 2005, 05:19:42 AM by eddieq »
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Offline Mitch

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Re:Organometallic Chemistry
« Reply #9 on: January 06, 2005, 12:36:15 PM »
I've actually made it.  ;)
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Offline Winga

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Re:Organometallic Chemistry
« Reply #10 on: January 06, 2005, 11:40:43 PM »
Is it
di-u-chlorodichlorobis(triphenylphosphine)palladium(II)?
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Offline Winga

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Re:Organometallic Chemistry
« Reply #11 on: January 06, 2005, 11:44:50 PM »
Quote from: AWK on January 05, 2005, 08:36:23 AM
2. Na[Au(CN)2 ]
Au - aurate
Ag - argentate

dinitrate - not abreviated form
e.g. calcium nitrate, we can omit "di-", right? How about [Co(NH3)4(H2O)Br](NO3)2?
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Offline AWK

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Re:Organometallic Chemistry
« Reply #12 on: January 07, 2005, 03:51:18 AM »
di-u-chloro-af-dichlorobis(triphenylphosphine)palladium(II)?  The rest is OK

Calcium nitrate is unambiguous because Ca shows oxidation state +2 only, but iron nitrate is ambiguous. Eearlier we used ferrous and ferric to distinguish between two oxidation states, now we use Fe(II) or Fe(III) or iron dinitrate (trinitrate). Using both indications, ie  iron(III) trinitrate is not an error.

[Co(NH3)4(H2O)Br](NO3)2
tetraammineaquabromocobalt(III) nitrate or dinitrate
« Last Edit: January 07, 2005, 04:06:22 AM by AWK »
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Offline Winga

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Re:Organometallic Chemistry
« Reply #13 on: January 08, 2005, 02:31:37 AM »
What's meant by -af-?
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