arent they more like blueish?
anyway, if u want to generate some copper ions through the method u first mentioned, u'll need 2 electrodes, an inert one at the cathode (something that can conduct electricity but not dissolve in water, example is graphite) and copper at the anode.
connect a battery with the cathode connected to the negative side of the battery (-) and the anode to the positive side of the battery (+)
copper ions would be formed at the anode (u shld see the anode "dissolving" in water. for the cathode, hydrogen may be produced, so be sure to keep the cathode out of harm's way.