There is actually a second fission stage which results in much of the energy.
First, the (relatively small) fission trigger goes off, releasing large amounts of electromagnetic radiation.
This bounces off the outer casing of the weapon, which is made of U-238.
The radiation is reflected inward, and this generates the conditions (temperature, pressure) to fuse the hydrogen isotopes.
The fusion reaction releases lots of high energy neutrons. These, unlike those emitted from the fission trigger,
are energetic enough to fission the U-238 of the outer case. (U-238 normally doesn't fission, it needs something like 1 MeV extra energy besides the new neutron to fission, but the fusion-produced neutrons have this energy).
This second round of fission (of the U-238 casing) is indeed responsible for a big chunk of the total energy release. (It is also responsible for tremendous amounts of radioactive fallout.) I don't know any solid percentages, however.