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Topic: Naming compunds  (Read 7239 times)

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Offline organ_ic

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Naming compunds
« on: August 20, 2006, 06:06:04 AM »
Hi there

can someone please answer these (probably dumb) questions

is 2-butanol the same as butan-2-ol??
3-chloro-penten-2oic acid the same as 3-chloro-2-pentenoic acid?

Thanks
organ_ic

Offline Albert

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Re: Naming compunds
« Reply #1 on: August 20, 2006, 06:35:12 AM »
Yes, they are just different ways of naming the same molecule. And this is not a dumb question. :)

Offline organ_ic

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Re: Naming compunds
« Reply #2 on: August 20, 2006, 06:48:01 AM »
hey there

thanks for the reply...umm its wrong to say...3-chloro-pent-2-enoic acid right? cos the suffix has to be oic aye?

and another thing i just came across a question where it tells me to draw trans -1,3-dichlorocyclohexane and so I thought seeing as its trans both substituents have to be either BOTH axial or BOTH equatorial but in the answer it has one of each-why!! am i missing something?

Thanks
organ_ic

Offline xiankai

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Re: Naming compunds
« Reply #3 on: August 20, 2006, 07:37:12 AM »
Quote
is 2-butanol the same as butan-2-ol??
according to IUPAC nomenclature, the latter is prefered to avoid ambiguity (people may think u have left out the prefix, etc.)

Quote
3-chloro-penten-2oic acid
did u mean 3-chloro pentan-2-oic acid? because the 'e' suggests the presence of an alkene group, which should be included in the prefix and not the suffix.

Quote
3-chloro-penten-2oic acid the same as 3-chloro-2-pentenoic acid?
same as above, former is prefered.

Quote
its wrong to say...3-chloro-pent-2-enoic acid right? cos the suffix has to be oic aye?
while the meaning gets across in both compounds (vaguely), the one that u called 'wrong' is not the proper way of naming, so yes the suffix has to be -oic :P
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Offline P-man

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Re: Naming compunds
« Reply #4 on: August 20, 2006, 10:47:01 AM »
Quote
is 2-butanol the same as butan-2-ol??
according to IUPAC nomenclature, the latter is prefered to avoid ambiguity (people may think u have left out the prefix, etc.)

Don't you mean former? As in the first one mentionned? Because that is always how I have seen it. 2-butanol.
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Offline xiankai

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Re: Naming compunds
« Reply #5 on: August 20, 2006, 10:50:33 AM »
thats weird. my lecture notes taught it as butan-2-ol. i'll look up IUPAC later.
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Offline Will

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Re: Naming compunds
« Reply #6 on: August 20, 2006, 10:52:15 AM »
xiankai is right I think. The 2 being before th -ol means that it is definitely referring to the hydroxyl. I always write it out as butan-2-ol.

Offline P-man

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Re: Naming compunds
« Reply #7 on: August 28, 2006, 09:09:29 AM »
Yeah, I guess it's true. I have also seen it as butan-2-ol.  :P
Pierre.

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