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Topic: Recrystallization  (Read 6437 times)

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Offline Sis290025

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Recrystallization
« on: September 12, 2006, 10:39:38 PM »
a. The following solvent selection data were collected for impure solid (A):

Solvent-------------Solubility at room temp.-----Solubility when heated--------------------Crystals formed when cooled

Methanol------------Insoluble------------------------Insoluble------------------------------------------(-)
Ethyl acetate-------Insoluble-----------------------Soluble-------------------------------------------very few
Cyclohexane--------Insoluble------------------------Soluble-----------------------------------------many
Toluene--------------Insoluble------------------------Soluble-----------------------------------------very few

Based on these results, what solvent or mixture of solvents might one consider using to recrystalline solid A?

I would choose cyclohexane as a solvent since the solute dissolves in hot solvent and crystals appear when the solvent is cool.  ???


b. The following is for impure solid B.


Solvent---------Solubility at room temp.-----Solubility when heated----------------Crystals formed when cooled

Water------------------Soluble-------------------------------(-)------------------------------------------(-)
Ethanol-----------------Soluble------------------------------(-)-------------------------------------------(-)
Dichloromethane----Insoluble------------------------Insoluble----------------------------------------(-)
Petroleum ether-----Insoluble------------------------Soluble-----------------------------------------very few
Toulene-----------------Insoluble------------------------Soluble-----------------------------------------many

Based on these results, what solvent/mixture of solvents might one consider using to rescystallize B?
I would choose toulene as a solvent since the solute dissolves in hot solvent and crystals appear when the solvent is cool.  ???

Thank you.
« Last Edit: September 12, 2006, 10:54:30 PM by Sis290025 »

Offline mike

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Re: Recrystallization
« Reply #1 on: September 12, 2006, 10:51:34 PM »
What is the question? ???
There is no science without fancy, and no art without facts.

Offline Sis290025

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Re: Recrystallization
« Reply #2 on: September 12, 2006, 10:55:46 PM »
I just modified it. (I'm sorry! :-[)

Offline mike

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Re: Recrystallization
« Reply #3 on: September 12, 2006, 11:02:59 PM »
Looks right to me.
There is no science without fancy, and no art without facts.

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