We want to determine the actual molarity of an unknown sample H2SO4. Therefore we titrate the unknown sample with NaOH (1M, f = 1.002).
2 NaOH + 1 H2SO4 → 1 Na2SO4 + 2 H2O
Valid at the equivalence point:
2x #mmol H2SO4 = 1x #mmol NaOH
Suppose you titrate 20.00 ml H2SO4 with 11.00 ml NaOH. What is then the actual molarity of the sulfuric acid (in mmol / ml)?
molarity = n / V
V H2SO4 = 20.00 mL
How do i find n?
n NaOH = m x V
= 1 x 11 = 11 moles
and then 2x #mmol H2SO4 = 1x #mmol NaOH
so 11 x 2 = 22 mmole H2SO4
thus m = 22 / 20 = 1,1 mmoles/mL ?