Plus is there an easy way to identify the changes in oxidation states in these equations?
A- Mg(s) + FeSO4(aq) --> Fe(s) + MgSO4
B- 2 HNO3(aq) + 3 H2S(aq) ---> 2 NO(g) + 3 S(s) + 4 H2O(l)
For A, you have to remember two easy rules to determine the oxidation state of metals:
1) the oxidation state of the pure metal is 0
2) the oxidation state of a metal ion is equal to its charge
For B, you can figure out the oxidation states of the N and S by using another set of simple rules (these rules are applicable to redox reactions involving non-metals, the other set of rules are for redox reactions with metals):
1) the oxidation state of oxygen is almost always -2 (exceptions: peroxides and superoxides)
2) the oxidation state of hydrogen is almost always +1 (except when in an ionic compound with a metal)
3) the sum of the oxidation states of the atoms in a molecule is equal to its charge
For example, in HNO
3, an uncharged molecule, you know that:
ON
H + ON
N + 3ON
O = 0
where ON
H = the oxidation state of H in HNO
3ON
N = the oxidation state of N in HNO
3, etc.
By rules (1) and (2), we know that ON
H = +1 and ON
O = -2. Therefore:
1 + ON
N + 3 x (-2) = 0
By simple algebra, you can find ON
N = +5
Repeat this process for the other compounds in the reaction to find how the oxidation states change for all atoms involved.