Oh, it's
thallium. I thought you meant titanium, but were spelling Ti with a capital I. (Especially as you also wrote CE for cerium at first.) Do make an effort to be accurate in typing.
The first two reactions overall give
2Ce
4+ + Mn
2+ 2Ce
3+ + Mn
4+(though writing it as two reactions implies that it occurs in two steps, not one.)
Combined with the third reaction, the overall process is
2Ce
4+ + Tl
+ 2Ce
3+ + Tl
3+Note that there are no Mn species in this equation because you start with Mn
2+ and end with Mn
2+ (though it gets oxidised to Mn
4+ and reduced back to Mn
2+).
What do you think is the catalyst in all this?