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Topic: supramolecules (Read 3870 times)
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renu
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supramolecules
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on:
October 12, 2006, 05:43:14 AM »
hi,wanted to ask out of spherands & corands which would have higher affinity for alkali metal ions & why???kindly describe taking into account pre-organisation & kinetic, thermodynamic selectivity
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swati
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Re: supramolecules
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October 12, 2006, 05:50:27 AM »
I am not sure whether I am correct o not, but spherands are more rigid thus more preorganised, thereby have high binding constant than corands. So spherands should have high affinity for alkali metals than corands.
Am I correct ?
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