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Topic: Adding reagents slowly over a reaction  (Read 912 times)

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Naruto

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Adding reagents slowly over a reaction
« on: December 10, 2021, 05:09:23 PM »
I'm doing a reaction where the procedure calls to add one of the reagents slowly over the course of 30 minutes to the reaction flask, but why would you do this instead of adding it all at once?  If necessary, I can copy/paste the procedure here.  Thanks!

Offline Corribus

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Re: Adding reagents slowly over a reaction
« Reply #1 on: December 10, 2021, 05:38:03 PM »
It usually comes down to favoring a desired product or influencing reaction rate. E.g.:
(1) so that one reactant is always in large excess, which can favor, e.g., monosubstitution vs disubstitution
(2) if the reaction is very exothermic...
What men are poets who can speak of Jupiter if he were like a man, but if he is an immense spinning sphere of methane and ammonia must be silent?  - Richard P. Feynman

Offline Babcock_Hall

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Re: Adding reagents slowly over a reaction
« Reply #2 on: December 11, 2021, 10:14:25 AM »
@OP,
Corribus gave a good answer.  Another thing to consider: when a reaction is being held below room temperature, one wants to avoid adding a new reagent (presumably which itself is at room temperature) too quickly, or the reaction will no longer be at the temperature one desires.

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