pH drops more
pH = 2,1 + log (0,025/0,075) = 1,62
Molarity = 0,1 M
And now, what should it proof, pH is changed more and molarity is in this case the same but ratio phosphate and phosphoric acid is different.
The only thing what we can say it is possible to have a constant molarity with different pH by choosing different ratios of phosphate and phosphoric acid.
But it doesn't say if I add some phosphoric acid to a phosphate solution the molarity will be the same, only if molarity of both compounds are the same.
At least M total = M(H3PO4) - M(H2PO4-) + (MH2PO4-) - M(H3PO4)
0,1 = 0,05 + 0,05
0,1 = 0,025 + 0,075
0,1 = 0,01 + 0,09
etc.
pH will result in the quote in HH equation.