1. Sulfantimonite is mostly likely sulphur antimonite. Antimonite is Sb
2S
32. Normal highest valence would probably pointing towards Ferrate(III). So you'll need the Barium ferrate(VI) complex which happens to be BaFeO
4.
3. It's a metal comlex with sodium center, single hydrogen ligand (monohydrogen), thioarsenite ligand (AsH
3O
2S
3-) and seven water ligands (heptahydrate).
4. Same as above except the center is potassium and ligands are a bit diffrent. hypothio is HSO
- and bismuthite is Bi
2S
35. This is a bit nasty one. A trinuclear metal complex with Fe, Co and Ni centers. Dihypothio is S
2O
2- and phosphite is PO
33-. These should give enough clue to balange it out using the
18 electron rule.