it is easiest to take volume out of the equation first, so that you can deal with moles only.
since c = n/v,
K
c = [CH
4][H
2O]/[H
2]
3[CO]
= {CH
4}{H
2O}/{H
2}
3{CO} * (1/V)
-2where let us take {A} to be the number of moles of A. and V to be the volume of the system.
so we have 3.92 = x
2/(1-x)(3-3x)
3.
im not sure if your method works fine, though since i never particularly paid much attention to my physical chemistry lectures and i prefer my method any day, its your choice.
now for the mathematical part... (im using my formula, you could change it to yours without much difficulty i should think)
3.92 = x
2/(1-x)(3-3x)
33.92 = x
2/(1-x)(1-x)
3(3)
3105.84 = x
2/(1-x)
410.29 = x/(1-x)
210.29 = x/(1-2x+x
2)
10.29 -20.58x + 10.29x
2 = x
10.29x
2 -21.58x +10.29 = 0
you can solve the quadratic equation henceforth...