January 12, 2025, 07:10:28 AM
Forum Rules: Read This Before Posting


Topic: Solubility problem  (Read 3726 times)

0 Members and 3 Guests are viewing this topic.

Offline Serenagreene

  • Regular Member
  • ***
  • Posts: 44
  • Mole Snacks: +3/-0
Solubility problem
« on: March 07, 2007, 10:14:49 PM »
Okay what am I doing wrong???

The Ksp of Iron (III) hydroxide is 8 * 10^-16.  How many ug of iron (III) hydroxide could be dissolved in 250 ml of solution?

Fe(OH)3 <--> Fe + 3 OH

Ksp = [Fe][OH]^3

8 * 10^-16  = X^4

X = 1.68 M

1.68 E^-4 = x/.250
x = 4.2 E^-5 moles * 106.87 g/mol = 4.49 E^-3 g

Teacher answer is 131 ug.

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27895
  • Mole Snacks: +1816/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Solubility problem
« Reply #1 on: March 08, 2007, 03:02:05 AM »
8 * 10^-16  = X^4

Why x4? Are concentrations of Fe3+ and OH- identical?
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline Serenagreene

  • Regular Member
  • ***
  • Posts: 44
  • Mole Snacks: +3/-0
Re: Solubility problem
« Reply #2 on: March 08, 2007, 08:00:07 AM »
Okay there was one problem.  I forgot that the 3 OH translates to a [3 OH}^3

So Ksp = [Fe][3 OH]^3
8E-16 = 3x^4
x =  1.28E-4 M  (I also dropped off the E-4 last night

1.28E-4 = x/.250

x = .093 moles * 106.87 g/mol = 9.95 g

Still a long way from the teacher's answer of 131 ug.


Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27895
  • Mole Snacks: +1816/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Solubility problem
« Reply #3 on: March 08, 2007, 02:54:37 PM »
Where did you get Kso value from?

Your math is still wrong, although you are a step closer.

[OH-] = 3[Fe3+]

[OH-]3 = (3[Fe3+])3 = ?
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline Serenagreene

  • Regular Member
  • ***
  • Posts: 44
  • Mole Snacks: +3/-0
Re: Solubility problem
« Reply #4 on: March 09, 2007, 05:06:17 AM »
The Ksp figure came from the teacher's problem. 

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27895
  • Mole Snacks: +1816/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Solubility problem
« Reply #5 on: March 09, 2007, 07:49:32 AM »
it is about 20 orders of magnitude off.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Sponsored Links