The correct name is 2,2,4-trimethylpentane, to which is given the common name of iso-octane (in industry).
The octane number scale measures the anti-knocking properties of gasoline (the greater that number, the lower will be the tendency for gasoline to auto-detonate). In that scale, it is attributed the value 100 to iso-octane (because it has a low tendency to auto-detonate) and the value 0 to n-heptane (which has a high tendency to auto-detonate). So, a gasoline with octane number 95 for example (which is the type of gasoline that my car drinks) has a similar behavior to a mixture composed of 95% of iso-octane and 5% n-heptane.