does that mean that if the chemical is packed in that material there will be absolutely no leak in any form(smell)
I suppose that this is theoretically possible to do, but it relies on a perfect seal, and no contamination on the outside of the package while you were putting it into the contianer.
I'm not familiar with these chemical resistance charts, but I don't think that chemical resistance would necessarily be an indicator of permeability. That would have more to do with the structure of the material. For example, a cotton T-shirt is chemically resistant to nitrogen gas, but permeable to it because the fibres are far apart in comparison to the size of nitrogen molecules.
If the consequences of this "smell" being detectable are particularly unfavourable, I wouldn't bet on anything. Some compounds smells can be detected at extremely low concentrations, especially if you have some highly specialised equipment, for example: a dog's nose.