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Topic: Alkene Stability  (Read 10112 times)

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Offline amcavoy

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Alkene Stability
« on: November 07, 2007, 12:44:49 PM »
In considering relative stability of alkenes, my understanding is that

1. More-substituted alkenes are more stable than less-substituted alkenes,
2. Trans alkenes are more stable than cis alkenes, and
3. Conjugated alkenes are more stable than isolated alkenes.

Given this information, I would say that (in terms of stability), we have

trans-2,5-dimethyl-3-hexene > 2,3-dimethyl-2-hexene > 3-ethyl-3-hexene > 3-methyl-1-heptene.

However, the correct order is

2,3-dimethyl-2-hexene > 3-ethyl-3-hexene > trans-2,5-dimethyl-3-hexene > 3-methyl-1-heptene.

Why is this so?

Thank you.

Offline amcavoy

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Re: Alkene Stability
« Reply #1 on: November 07, 2007, 01:14:47 PM »
Oops, sorry for posting this, I figured it out.  I was looking at the wrong carbon atoms to determine the number of substituents.

Thanks  :)

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