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Topic: Calculating pH of sol'n  (Read 4111 times)

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Offline sh00tingstarz

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Calculating pH of sol'n
« on: November 20, 2007, 03:03:42 PM »
1.  Calculate the pH of 1.2 M HCl.

Work:       
-when I attempt this problem using -log(1.2) I get a negative pH which I know cannot be right.

2. Calculate the pH and pOH of a solution obtained from equal volumes of 0.10 M H2SO4 and 0.30 M NaOH.

 Work:   
 -the Ka of sulfuric acid is 1.03 x 10-2
    kb=kw/ka
   Therefore, kb of sulfuric acid is 1x10-14/1.03x10-2 = 9.7x10-13.  I'm not sure what else to do from there.

Offline Borek

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Re: Calculating pH of sol'n
« Reply #1 on: November 20, 2007, 05:09:23 PM »
I get a negative pH which I know cannot be right.

So you have to learn something new - pH can be negative.

Quote
Calculate the pH and pOH of a solution obtained from equal volumes of 0.10 M H2SO4 and 0.30 M NaOH.

Looks like limiting reagent question... Hint: it was a hint ;)
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Offline agrobert

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Re: Calculating pH of sol'n
« Reply #2 on: November 20, 2007, 07:41:36 PM »
This should clear up negative pH

http://antoine.frostburg.edu/chem/senese/101/acidbase/faq/negative-pH.shtml

2

Write the chemical reaction.  What is the concentration of H+?  Calculate pH from this and then subtract from 14 for pOH.
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