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Topic: Quick pH question  (Read 6147 times)

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Offline jalen

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Quick pH question
« on: December 25, 2007, 11:12:06 AM »
Calculate the pH of a sample of vinegar that contains 0.83mol/L acetic acid. What is the percent dissociation of the vinegar?

Ka = [CH3COO][H3O] / [CH3COOH]
    = x x / [0.83-x]
    = 1.8 x 10-5[/s]

[CH3COOH] = 0.83
          Ka      1.8 x 10-5
                   = 4.6 x 104

Quadratic answer: x=3.86 x 10-3

pH = -log(3.86 x 10-3)
     = 2.41

Q: How do you get the percent dissociation of the vinegar? Please show steps. Thank you.

Offline Borek

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Re: Quick pH question
« Reply #1 on: December 25, 2007, 12:21:52 PM »
pH is OK.

For % dissociation just use definition - you know how much acid dissociated ([CH3COO-] = [H3O+]), you know how much acid is present.

http://www.chembuddy.com/?left=pH-calculation&right=introduction-acid-base-equilibrium

Percent dissociation and dissociation fraction are the same thing.
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