Potassium iodide is fairly easy to obtain. Get an iodide solution at your local pharmacy; many of them contain an alcohol solvent with potassium iodide dissolved in it. Just boil that off and you get a fine crystal powder of KI. If you're looking for something to do with this, it reacts very visibly with hydrogen peroxide (even 3%), which is an example of oxidation into products which then react further. Not sure how you may use that, but it's something I did a few weeks ago. It could possibly be an example of a reaction creating products which then react further than you wanted.
Not sure whether you have any sodium hydroxide around (lye), since it's not exactly common in the home anymore, but if you do, it reacts with vinegar to yield sodium acetate and water (and CO2?). I won't bother figuring out exactly what it would be, but the yield would be small considering the only 5% or so of vinegar that is acetic acid.
Hopefully that helps a little bit. Requires a little bit of preparation, but I figured I'd share what I know