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Topic: Me3-SiCl-NaI-CH3-CN An efficient reducing agent for benzyllic alcohols  (Read 3298 times)

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Offline thorium

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Me3-SiCl-NaI-CH3-CN An efficient reducing agent for benzyllic alcohols
« on: February 02, 2008, 06:55:41 PM »
Can anyone provide me some info about this reagent and its cas nr?
« Last Edit: February 02, 2008, 07:42:02 PM by thorium »
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Offline lutesium

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Re: Me3-SiCl-NaI-CH3-CN An efficient reducing agent for benzyllic alcohols
« Reply #1 on: February 02, 2008, 07:54:43 PM »
I've read at a paper that its a common reagent used in organic reactions but I've never seen an example other than:

Tetrahedron Letters, Vol. 28, No. 33,pp 3817-3818-3819


Lutesium...
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Offline sjb

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Re: Me3-SiCl-NaI-CH3-CN An efficient reducing agent for benzyllic alcohols
« Reply #2 on: February 03, 2008, 03:33:59 PM »
Other than the reference already cited, don't forget that it's a mixture of Me3SiCl, NaI and CH3N, not one big molecule ;)
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