4s orbital , according to n+l rule , should get filled before 3d .
this will lead to 3d4 state which is unsymmetrical than 3d5 this is most symmetrical possible state, thus to get maximum possible symmetry in order to get max. posible stability, the 4s electron is raised to 3d level to get 3d5 state.
Sorry, I have answered in quite complecated way.
thanx
hrushikesh