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Topic: Special Cyclopropane  (Read 5546 times)

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Offline dm164

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Special Cyclopropane
« on: March 09, 2008, 10:03:12 PM »
I would like to know if two adjacent carbons can be bonded to an oxygen in a cyclopropane; creating C3H4O. I am not sure if the distance between the oxygen and carbons are too far to make it possible. Another similar to the same idea is if all 3 carbons bond to a single nitrogen (C3H3N) would that also be possible?

Offline agrobert

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Re: Special Cyclopropane
« Reply #1 on: March 09, 2008, 10:53:36 PM »
What research have you done for this topic?  Try naming them.  The geometry of these compounds is acceptable but do expect the compounds to be isolated at STP?
In the realm of scientific observation, luck is only granted to those who are prepared. -Louis Pasteur

Offline AWK

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Re: Special Cyclopropane
« Reply #2 on: March 10, 2008, 02:10:56 AM »
do you mean these compounds? They are known
AWK

Offline macman104

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Re: Special Cyclopropane
« Reply #3 on: March 10, 2008, 02:23:46 AM »
I would like to know if two adjacent carbons can be bonded to an oxygen in a cyclopropane; creating C3H4O. I am not sure if the distance between the oxygen and carbons are too far to make it possible. Another similar to the same idea is if all 3 carbons bond to a single nitrogen (C3H3N) would that also be possible?
Do you mean, C2H4O?  As in...an epoxide?  I've attached my own revised pdf.  Just in case you had your formula wrong...

Actually, i just thought of this compound for your C3H4O compound, it's attached as well.  it also meets your criteria of being the cyclopropane

EDIT:  Thanks to AWK for the pdf idea.  I hated making drawings in chemdraw and then having to shrink the huge dimension .PNG files it made, this is much easier :).

Offline dm164

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Re: Special Cyclopropane
« Reply #4 on: March 10, 2008, 08:19:10 PM »
The two drawings macman has provided are correct, but I am not refering to the epoxide in his cyclos.pdf.  I am not sure of how these would be named and I have never heard them to known. I expect that compounds will need pressure and heat in order for their creation, but I do not have any idea of their properties. Well, probably explosive.
I would like to know how stable the bonds would be.

Offline macman104

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Re: Special Cyclopropane
« Reply #5 on: March 10, 2008, 09:45:51 PM »
I've reattached them in this post in one pdf for you.  Also with the name of the oxygen containing compound from chemdraw.  However, it hadn't a clue how to name the nitrogen containing compound, nor how to name the nitrogen compound if it were simply 4 carbons.  I would imagine being able to make the oxygen compound as I'm pretty sure the existence of the bicyclo[1.1.0]butane is known, so the oxygen analog I think would be possible.  However, I've not a clue about the nitrogen compound.

Offline sjb

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Re: Special Cyclopropane
« Reply #6 on: March 11, 2008, 05:14:12 AM »
If the nitrogen-containing compound had no nitrogen, I think it's tetrahedrane, or tricyclo[1.1.0.02,4]butane. So a semisystematic name could be monoazatetrahedrane, or monoazatricyclo[1.1.0.02,4]butane ??

http://en.wikipedia.org/w/index.php?title=Tetrahedrane&oldid=192376659

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