the one that you are talking about having multiple layers is probably amorpheous cells, which are by the way the cheapest in the market, but also the least efficient, they also happen to be the easiest to make, what determines a cell from being amorpheous, polycrystalline or crystalline is the cooling rates, the longer you let it cool the more efficient it will become, so an amorpheous is about 5-7% efficient, however, in an amorpheous solar cell you put the cells in layer to increase the efficiency.
Another advantage with amorpheous solar cells is that you can actually bend the cells, unlike polycrystalline and crystalline cells they are very brittle and so thin such that the smallest amount of bending would immidiately break them. One of the reasons that solar cells are so expensive is the production cost, they have to be assembled manually, so maybe if there is more awareness to this technology such as there was for computers and for inverters when they were worth hundreds of times more than such technology is worth now then the cost of a solar cell would eventually fall in the market as production increases.
they all consists of impurities of 1 part per million of both boron and phosphorous for the positive layers and negative layers and a layer in the center called the intrinsic layer just about a few molecules of lenght composed of silicon. The silicon used in a solar cell has to be atleast 99% pure, and the formula that is involved in purifying silicon is as follows:
2SiO + C + 2000
oC ---> Si + CO
2and since silicon is the second most abundant element on earth there goes my theory above.
about putting the solar cell to send electricity in salt water i do not know but i think that this could cause some hard to the cells and in time decrease the efficiency even more. Perhaps you should do something around that area to decrease the chance of that occurying.
there is another kind of cell that has a really high efficiency of about 35% and that is germanium cells, the problem is the production is very dirty and would really be more dangerous.