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Topic: New isotope effect  (Read 30053 times)

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Offline gippgig

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New isotope effect
« on: June 16, 2008, 02:11:38 AM »
A major exception to the general rule that isotopes have very similar chemical properties has been found. Hydroxymethylene (H-C=O-H) has been discovered by high-vacuum flash pyrolysis of glyoxylic acid (HCOCOOH) & isolation in a cryogenic matrix (Nature vol. 453 page 906). HCOH spontaneously rearranges to formaldehyde (H2CO) with a half-life of about 2 hours. However, the deuterated form HCOD is stable under the same conditions and has a calculated half-life of over 1000 years. The difference appears to be because HCOH rearranges by an unusual quantum mechanical tunnelling process.

deiveegan

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Re: New isotope effect
« Reply #1 on: July 23, 2008, 09:30:49 AM »
Dear Sir,

Formaldehyde is very dangerous and irritating and sometimes this will affect cancer i think pls confirm this one

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