The lab equipment that we use to make measurements is never perfect and has only a limited precision. In the case of your balance, if you had two pennies that differed in weight by less than 0.0001g, then the balance would not be able to tell them apart. Hence, the balance contributes ± 0.0001 g to the standard deviation of your measurements. If your standard deviation is equal to or less than that uncertainty, your experimental error can be attributed to the precision (or lack thereof) of the balance. If not, some other factors contributed to the standard deviation (e.g. deviations in the actual weights of the pennies themselves).