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Topic: Titration Problem  (Read 8084 times)

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Offline sergii

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Titration Problem
« on: October 12, 2008, 12:45:20 PM »
I'm having a big problem in a chemistry experiment and have no idea how to solve it. I was given a carbonate from Group 1 : X2CO3 were X is unknown. The purpose of the experiment is to find X.

I weighed out 0.99g of the carbonate, dissolved it in distilled water and made the solution up to 100.00cm^3. I took out 10.0cm^3 portions and titrated with 0.100 moldm^-3 HCl.

I carried out a titration and found that the average titre was 32.67 cm^3.

The equation for the reaction would be -

X2C03 + 2HCl = 2XCl + CO2 + H20

Does anyone know how i can find X?

Offline Borek

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Re: Titration Problem
« Reply #1 on: October 12, 2008, 01:03:58 PM »
Find number of moles of X2CO3 - that plus mass of the sample will give you molar mass of carbonate. That identifies X.
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Offline sergii

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Re: Titration Problem
« Reply #2 on: October 12, 2008, 01:54:31 PM »
I add the mass of the sample to the number of moles? 0_o

Offline sergii

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Re: Titration Problem
« Reply #3 on: October 12, 2008, 02:07:51 PM »
How do i find the number of moles?

Offline sjb

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Re: Titration Problem
« Reply #4 on: October 12, 2008, 04:43:55 PM »
How many moles of HCl did you use up in the titration?

Offline sergii

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Re: Titration Problem
« Reply #5 on: October 13, 2008, 05:24:49 AM »
It was 0.100 moles of HCl and the average titre was 32.67cm3. So i think the amount of HCl used was 3.267 x 10-3mol

Offline Borek

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Re: Titration Problem
« Reply #6 on: October 13, 2008, 09:09:43 AM »
So i think the amount of HCl used was 3.267 x 10-3mol

OK, now, from this information and reaction equation - how many moles of carbonate?
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Offline sergii

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Re: Titration Problem
« Reply #7 on: October 14, 2008, 05:09:47 AM »
Half?

Offline Borek

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Re: Titration Problem
« Reply #8 on: October 14, 2008, 05:21:36 AM »
Half of what?
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Offline lann

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Re: Titration Problem
« Reply #9 on: October 14, 2008, 09:54:22 AM »
If you have the moles of HCl, then you can easily find the moles of the X2CO3.

X2C03 + 2HCl = 2XCl + CO2 + H20

The ratio of X2CO3 to HCl is 1:2.

Let y be the number of moles of X2CO3.
1 mole X2CO3 / 2 moles HCl = y mol of X2CO3 / 3.267 x 10-3mol of HCl

When you get y, you can find the Molecular Mass (g/mol) of X2CO3.
0.99 g / MM of X2CO3 = y

Then, when you get MM of X2CO3, you can get the MM of X since you know the MM of C and MM of O.  You will do simple math in this case.

I just got the idea due to Borek and sjb's help.  I hope I'm correct.

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