Ok, well if you look at Ha&b, they are next to oxygen right? Can you predict which way the electrons are going to be pulled?
Well, there are two ways, usually in your book there is a table, of common chemical shifts, you can use that to look at where the peaks should be. Otherwise, we can continue discussing how to take a guess at the order they appear (and where they are) in the NMR. However, you will need to memorize a few values in that table, so you can have some idea where things are in the NMR.