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Calculating the pH of an acidic salt
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Topic: Calculating the pH of an acidic salt (Read 5695 times)
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student8607
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Calculating the pH of an acidic salt
«
on:
March 03, 2009, 02:27:59 PM »
I'm fine when I'm given the concentration + the Ka value, but how would I solve for the pH of this:
0.25M NH
4
Br
?
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Borek
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Re: Calculating the pH of an acidic salt
«
Reply #1 on:
March 03, 2009, 02:51:57 PM »
NH
4
+
- what's that?
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ChemBuddy
chemical calculators - stoichiometry, pH, concentration, buffer preparation,
titrations.info
student8607
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Re: Calculating the pH of an acidic salt
«
Reply #2 on:
March 03, 2009, 03:04:59 PM »
Ammonium?
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sjb
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Re: Calculating the pH of an acidic salt
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Reply #3 on:
March 03, 2009, 03:53:46 PM »
OK, so what's the Ka of the ammonium ion?
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student8607
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Re: Calculating the pH of an acidic salt
«
Reply #4 on:
March 03, 2009, 04:16:00 PM »
5.6 x 10
-10
I got it now. (pH of 4.92)
The Ka is always given in the book so I assumed there was another way to do it since the Ka wasn't given.
Thanks.
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AWK
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Re: Calculating the pH of an acidic salt
«
Reply #5 on:
March 04, 2009, 12:56:15 AM »
K
a
x K
b
= K
w
(always, so you can calculate it)
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AWK
Borek
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Re: Calculating the pH of an acidic salt
«
Reply #6 on:
March 04, 2009, 03:38:01 AM »
edit: deleted to not confuse anyone
«
Last Edit: March 04, 2009, 05:21:03 AM by Borek
»
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ChemBuddy
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AWK
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Re: Calculating the pH of an acidic salt
«
Reply #7 on:
March 04, 2009, 05:01:30 AM »
pH is OK I got 4.91 using activities
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AWK
Borek
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Re: Calculating the pH of an acidic salt
«
Reply #8 on:
March 04, 2009, 05:20:34 AM »
Sorry, ignore my post, I have flipped everything 180 deg
Quote from: AWK on March 04, 2009, 05:01:30 AM
pH is OK I got 4.91 using activities
IS=0.25, have you used Davies equation, or something?
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ChemBuddy
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AWK
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Re: Calculating the pH of an acidic salt
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Reply #9 on:
March 09, 2009, 02:55:59 AM »
I used aq_solution recommended by IUPAC. It use Millero-Pitzer method for calculation of activity coefficients
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AWK
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Calculating the pH of an acidic salt