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Topic: Enthalpy question PLS HELP  (Read 3133 times)

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Offline appleseed

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Enthalpy question PLS HELP
« on: April 15, 2009, 10:38:10 PM »

Hello! I cant seem to work out the question because there doesnt seem to be enough info given! how can i get the enthalpy values from the spontaneity info given ! grrr..
any help would really be appreciated!!
cheers!


QUESTION
consider the following two reactions
2Fe(s) + O2(g)---> 2FeO(s)                       Delta G (standard conditions) : -450kJ/mol at 500K             
2CO (g) +O2 (g)---> 2CO2(g)                      Delta G (standard conditions) : -480kJ/mol at 500K

use hess's law to determine Delta G (at standard condition) for the reaction :
2FeO(s) +2CO(g)---> 2Fe(s) +2CO2(g)

Offline Vidya

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Re: Enthalpy question PLS HELP
« Reply #1 on: April 16, 2009, 04:29:29 AM »
No need of calculating delta H here
combine both the equations and add up delta G using hess's law.

Offline UG

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Re: Enthalpy question PLS HELP
« Reply #2 on: April 16, 2009, 08:07:21 PM »
Reverse equation one and then add the two together:

2FeO  :rarrow: O2 + 2Fe                    +450kJ mol-1
2CO + O2  :rarrow: 2CO2                   -480kJ mol-1

The O2 will cancel out giving you:

2FeO +2CO  :rarrow: 2Fe +2CO2

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