So are you saying that less polar molecules that are less likely to have intermolecular interactions are more likely to be in the gas phase whereas polar molecules that are interacting are more likely to be in the liquid because they are more stable there?
Yes! That is exactly what I'm saying (okay maybe not
exactly but close enough)
Less polar molecules aren't less likely to have intermolecular forces, they just have weaker ones, i.e. temporary/instantaneous dipole induced-dipole attractions, these dispersion forces are very weak, so the molecules are further apart from one another, making it more likely to be gaseous. Polar molecules have stronger intermolecular interactions,i.e. permanent dipole-dipole attractions, they are more likely to be a liquid or a solid because these attractions keeps the particles closer together so that less escapes, resulting in a liquid or a solid.