We are doing a general unknown. According to one of the tests it states that if the unknown solution dissolves/soluble in HCl, it means its an amine. When I told my teacher this and why I don’t have a NO2 mass in my combustion analysis sheet, she said that all you need is on the sheet she gave me.
Given
Unknown compound: 1.075g
CO2: 2.625g
H2O: 1.075g
Molecular weight: 72.104g
I did this…but the empirical formula doesn’t look right.
1) determine the mass of carbon, hydrogen, and oxygen in 1.575 g of compound.
carbon: 2.625 g x (12.01 / 44.01) = 0.7163 g
hydrogen: 1.075 g x (2.016 / 18.02) = 0.1203 g
oxygen: 1.075 – 0.7163 – 0.1203 = 0.2384 g
2) convert to moles.
carbon: 0.7163 / 12.01 = 0.0596 mol
hydrogen: 0.1203 / 1.008 = 0.1193 mol
oxygen: 0.2384 / 16 = 0.0015 mol
3) divide each molar amount by the lowest value to obtain small integers
carbon: 0.0596 / 0.0015 = 40
hydrogen: 0.1193 / 0.0015 = 80
oxygen: 0.0015 / 0.0015 = 1
The empirical formula of the substance is C40H80O.