December 28, 2024, 11:44:27 AM
Forum Rules: Read This Before Posting


Topic: major product  (Read 4490 times)

0 Members and 1 Guest are viewing this topic.

Offline orgoclear

  • Full Member
  • ****
  • Posts: 176
  • Mole Snacks: +9/-13
major product
« on: May 08, 2009, 01:38:24 PM »
When HBr reacts with pent-2-ene, then what is the major product? Please specify the reason for your choice.

Offline azmanam

  • Chemist
  • Sr. Member
  • *
  • Posts: 1416
  • Mole Snacks: +160/-24
  • Mediocrity is a handrail -Charles Louis d'Secondat
Re: major product
« Reply #1 on: May 08, 2009, 01:41:43 PM »
Knowing why you got a question wrong is better than knowing that you got a question right.

Offline orgoclear

  • Full Member
  • ****
  • Posts: 176
  • Mole Snacks: +9/-13
Re: major product
« Reply #2 on: May 08, 2009, 02:02:40 PM »
okay i am sorry. i am a new member. I can give the reasons why either of the two products. 2-bromopentane or 3-bromopentane can be the major one but i am unable to decide. 2-bromopentane has more hyperconjugative hydrogens when you consider the corresponding carbocation that is formed while the carbocation formed in 3-bromopentane is stabilised by inductive effects. I dont know how to decide which one will be major

Offline orgoclear

  • Full Member
  • ****
  • Posts: 176
  • Mole Snacks: +9/-13
Re: major product
« Reply #3 on: May 14, 2009, 03:16:21 AM »
i guess no answers  :'(

Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7976
  • Mole Snacks: +555/-93
  • Gender: Male
Re: major product
« Reply #4 on: May 14, 2009, 04:32:38 AM »
2-pentene is not a good example. You can get almost equal amounts of both isomers

http://www.personal.psu.edu/the1/addregi.htm
AWK

Offline orgoclear

  • Full Member
  • ****
  • Posts: 176
  • Mole Snacks: +9/-13
Re: major product
« Reply #5 on: May 14, 2009, 04:35:01 AM »
thanks. even i was thinking that almost equal amounts will be formed. Yet in the textbook, it is given that 3-bromopentane will be the major product. so thats where i had the doubt.

Sponsored Links