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Topic: is Aluminium Chloride Hexahydrate corrosive to metals?  (Read 7055 times)

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Offline jackybh

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is Aluminium Chloride Hexahydrate corrosive to metals?
« on: May 19, 2009, 11:33:42 PM »
I'm currently doing some research about AlCl3 for work. My research is related to how corrosive is a solution of 15% of aluminium Chloride Hexahydrate (in ethanol) to steel and/or stainless steel, or other metals. The thing is that we are going to put this solution in a spray applicator but it has a steel spring inside, so our concern is that after a few days the solution could eat the steel and leave the sprayer useless.

Hope you can help me out with this

Offline BluRay

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Re: is Aluminium Chloride Hexahydrate corrosive to metals?
« Reply #1 on: May 20, 2009, 03:11:01 AM »
It is more or less corrosive as a dilute solution of HCl. About your steel spring, it depends on the steel; it's difficult to give an answer.

Offline jackybh

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Re: is Aluminium Chloride Hexahydrate corrosive to metals?
« Reply #2 on: May 20, 2009, 09:34:01 AM »
it is called "316 stainess steel", is it strong enough to resist corrosion?

Which way would you test it?
I mean, how many hours/days should pass so I can be sure the spring would resist.

Offline UnintentionalChaos

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Re: is Aluminium Chloride Hexahydrate corrosive to metals?
« Reply #3 on: May 20, 2009, 12:56:21 PM »
Stainless steels are sensitive to pitting from anything containing chloride. I know from experience that concentrated HCl does quite a number on 316, so it stands to reason that more dilute stuff will just act slower.

http://en.wikipedia.org/wiki/Pitting_corrosion

Offline jackybh

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Re: is Aluminium Chloride Hexahydrate corrosive to metals?
« Reply #4 on: May 20, 2009, 01:26:13 PM »
So, now the question becomes:

How long will it take the 15% AlCl3 solution we are using to affect the "316 stainless steel" spring?
let's assume that the spring uses a string of 0,5mm width.

Offline sjb

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Re: is Aluminium Chloride Hexahydrate corrosive to metals?
« Reply #5 on: May 21, 2009, 02:27:43 AM »
Define "affects" - arguably it may be on the scale of milliseconds, just not noticeable for days?

Offline jackybh

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Re: is Aluminium Chloride Hexahydrate corrosive to metals?
« Reply #6 on: May 21, 2009, 10:07:38 AM »
Ok, I meant:

How much time would take the AlCl3 solution to destroy, consume, or break the spring so it becomes useless and the pump of the sprayer stops working?

Note: I have a spring submerged in the solution for 48hours now and there is no VISUAL (bare naked eye) sign or corrosion.

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