Let's assume you have 100g of the compound. 16.3g of it would be hydrogen and therefore 83.7 grams of it will be carbon. Number of moles of hydrogen in 16.3 grams = 16.3/1 = 16.3 moles
Number of moles of carbon = 83.7/12 = 6.975 moles
So the ratio of hydrogen to carbon is, 16.3 : 6.975 which can be simplified to 2.33 : 1
Make the ratios whole numbers and you'll have your emperical formula