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Topic: reduction  (Read 8105 times)

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Offline leeton

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reduction
« on: August 16, 2009, 03:47:49 AM »
 :(

who know the reduction?
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Offline Arctic-Nation

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Re: reduction
« Reply #1 on: August 16, 2009, 05:21:19 AM »
What are you asking here? Reducing agent? Reaction mechanism? Do you know any reagents that might transform an ester into an alcohol?
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Offline leeton

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Re: reduction
« Reply #2 on: August 23, 2009, 01:46:40 AM »
Quote from: Arctic-Nation on August 16, 2009, 05:21:19 AM
What are you asking here? Reducing agent? Reaction mechanism? Do you know any reagents that might transform an ester into an alcohol?

I want to know reagents of this reduction!
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Offline amdeigo

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Re: reduction
« Reply #3 on: August 23, 2009, 08:39:13 AM »
I think NaBH4/I2 is best choice!
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Offline Sam (NG)

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Re: reduction
« Reply #4 on: August 23, 2009, 10:22:01 AM »
What methods have you already tried?
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Offline jingzhang

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Re: reduction
« Reply #5 on: August 24, 2009, 12:44:40 AM »
LAH.
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Offline Arctic-Nation

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Re: reduction
« Reply #6 on: August 24, 2009, 09:38:25 AM »
As long as everyone's handing out ideas for free: LiBH4 with catalytic methanol in Et2O. Works like a charm when sensitive functional groups are around.
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Offline Med90

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Re: reduction
« Reply #7 on: August 30, 2009, 12:35:00 PM »
LAH or DIBAL-H
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Offline Fridushka

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Re: reduction
« Reply #8 on: August 30, 2009, 12:42:25 PM »
as i know, NaBH4 and LiAlH4 are the reagents that produce and alcohol (2 alcohol both 1o by reducing an ester...
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Offline leeton

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Re: reduction
« Reply #9 on: September 04, 2009, 09:30:02 AM »
Quote from: Sam (UoN) on August 23, 2009, 10:22:01 AM
What methods have you already tried?

LAH in Et2O, NaBH4 in Et2O/MeOH, I had used, but I still got no products!
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Offline Arctic-Nation

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Re: reduction
« Reply #10 on: September 04, 2009, 11:46:16 AM »
Do you get any reaction products, or do you just get the starting material back after the reaction? Maybe the phosphorine ring isn't stable under the common hydride conditions (or maybe it is, I've never used it or known it being used).
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Offline leeton

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Re: reduction
« Reply #11 on: September 07, 2009, 08:19:58 AM »
Quote from: Arctic-Nation on September 04, 2009, 11:46:16 AM
Do you get any reaction products, or do you just get the starting material back after the reaction? Maybe the phosphorine ring isn't stable under the common hydride conditions (or maybe it is, I've never used it or known it being used).

I really got some products, from TLC analysis, I found many pots and there was one lagging from starting line to the end.How can I got what I need? friend if you have any new ideas, please impress me, maybe we can really become friend.
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Offline song662309

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Re: reduction
« Reply #12 on: October 17, 2009, 03:34:19 AM »
my interest ,my msn is song662309@hotmail.com
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