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Topic: Molecular and Empirical Formula, Gas Laws  (Read 8653 times)

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Offline Naples

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Molecular and Empirical Formula, Gas Laws
« on: September 06, 2009, 12:51:34 PM »
1. A certain compound is composed of: 54.6% carbon, 9.0% hydrogen and 71.1% oxygen.  The molar mass of the compound is 90.0.  What are the empirical and molecular formulas of this compound?

C: 54.6g (1 mole / 12.01g) = 4.55 moles/4.44 moles = 1.02
H: 9.0g (1 mole / 1.01g) = 8.91 moles/4.44 moles = 2.01
O: 71.1g (1 mole / 16.00g) = 4.44 moles/4.44 moles = 1

So the formula would be CH2O...is that supposed to be the molecular formula or the empirical formula?


2. What mass of oxygen is contained in a 3.50 L tank where the temp is 50.0oC and the pressure is maintained at 4.5 atm?
I'm not really sure what formula I should be using to solve this.


3. What pressure will be exerted by each of the gases in the following mixture is the total pressure is 768.8 torr? .500g H2, .245g O2 and .335g N2
I know that PT = P1 + P2 + P3...but I'm unsure of how to apply that to find the pressure of each gas.

Offline Yggdrasil

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Re: Molecular and Empirical Formula, Gas Laws
« Reply #1 on: September 06, 2009, 01:23:52 PM »
1. A certain compound is composed of: 54.6% carbon, 9.0% hydrogen and 71.1% oxygen.  The molar mass of the compound is 90.0.  What are the empirical and molecular formulas of this compound?

C: 54.6g (1 mole / 12.01g) = 4.55 moles/4.44 moles = 1.02
H: 9.0g (1 mole / 1.01g) = 8.91 moles/4.44 moles = 2.01
O: 71.1g (1 mole / 16.00g) = 4.44 moles/4.44 moles = 1

So the formula would be CH2O...is that supposed to be the molecular formula or the empirical formula?

This is the empirical formula.  To find the molecular formula, you need to know the elemental composition and the molecular weight.

Quote
2. What mass of oxygen is contained in a 3.50 L tank where the temp is 50.0oC and the pressure is maintained at 4.5 atm?
I'm not really sure what formula I should be using to solve this.

First, use the ideal gas law to calculate the number of moles of oxygen.  You should then be able to calculate the mass of the oxygen when you know the number of moles.


Quote
3. What pressure will be exerted by each of the gases in the following mixture is the total pressure is 768.8 torr? .500g H2, .245g O2 and .335g N2
I know that PT = P1 + P2 + P3...but I'm unsure of how to apply that to find the pressure of each gas.

The partial pressure of each component (P1, etc.) are proportional to that component's mole fraction.  For example, PH2 = PT * (moles of H2) / (total moles of gas).

Offline Fridushka

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Re: Molecular and Empirical Formula, Gas Laws
« Reply #2 on: September 06, 2009, 03:51:05 PM »
here where the empirical formula is : CH2O..its molar mass is equal to 30, and when the molecular is 90, all you have to do is to divide 90 by 30..!

Offline DrCMS

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Re: Molecular and Empirical Formula, Gas Laws
« Reply #3 on: September 07, 2009, 02:21:51 PM »
1. A certain compound is composed of: 54.6% carbon, 9.0% hydrogen and 71.1% oxygen. 

Don't you think it's strange that you have 134.7% Carbon Hydrogen and Oxygen?

Offline Naples

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Re: Molecular and Empirical Formula, Gas Laws
« Reply #4 on: September 07, 2009, 02:30:59 PM »
Yeah I realized that, but it's a summer assignment so I can't really ask my teacher until tomorrow, when I have my first day of school!!!

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