December 26, 2024, 06:15:42 PM
Forum Rules: Read This Before Posting


Topic: Ferrocenium cation  (Read 8938 times)

0 Members and 1 Guest are viewing this topic.

Offline -SERS-

  • New Member
  • **
  • Posts: 6
  • Mole Snacks: +0/-0
  • Gender: Male
Ferrocenium cation
« on: October 01, 2009, 04:04:13 AM »
In my last lab we did various experiments with ferrocene and analysed similar compounds' 1H-NMR. One was the ferrocenium cation [(η5-C5H5)2Fe]+

Basically, I've been wondering why there's a broad signal at around 29.08ppm. Why is it this shape and at such a high chemical shift?

Offline Rudi

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +2/-0
  • Gender: Male
Re: Ferrocenium cation
« Reply #1 on: October 01, 2009, 11:21:05 AM »
Hi,

this is due to the paramagnetism of the cation.

Sponsored Links