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Topic: questions involving wavelengths and dissociation  (Read 10756 times)

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Offline pistaciolow

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questions involving wavelengths and dissociation
« on: October 07, 2009, 11:03:16 AM »
By using photons of specific wavelengths, chemists can dissociate gaseous HI to produce H atoms with accurately known speeds. When HI dissociates, the H atoms move away rapidly, whereas the relatively heavy I atoms move little.
A. If a photon of 256 nm is used, what is the excess energy (in J) over that needed for the dissociation?

E = hc/lambda
(1.9875 e-25)/(2.56 e-7) = 7.76e-19 J
Quote
Your answer differs from the correct answer by orders of magnitude.

B.If all of this excess energy is carried away by the H atom as kinetic energy, what is its speed (in m/s)?
no idea

Help?

Offline Borek

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Re: questions involving wavelengths and dissociation
« Reply #1 on: October 07, 2009, 11:20:27 AM »
What is formula for kinetic energy?
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Offline pistaciolow

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Re: questions involving wavelengths and dissociation
« Reply #2 on: October 07, 2009, 04:43:14 PM »
KE = ½mv². I'm thinking KE = the answer of part A and m=1.673 x 10^-27 kg, but I still haven't figured out the correct value for part A yet.

Offline plankk

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Re: questions involving wavelengths and dissociation
« Reply #3 on: October 07, 2009, 04:54:16 PM »
Look for value of energy, which is needed to dissociate HI.

Offline pistaciolow

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Re: questions involving wavelengths and dissociation
« Reply #4 on: October 08, 2009, 02:53:16 PM »
Bond dissociation energy?

This was also apart of the question: a.) What is the longest wavelength that can dissociate a molecule of HI.
406 nm

Bond dissociation energy=hv=h(c/wavelength)
BE=6.626e^-34 (3e^8*2.56 e-7)=7.76e^-19
BE=6.626e^-34 (3e^8*4.06 e-7)=4.896e^-19
7.76e^-19
-(4.896e^-19)
=2.86e^-19?

...And KE = ½mv².
=2.86e^-19=(1.673e^-24)v^2
                                  2
=2.86e^-19=(1.673e^-24)v^2
                                 2
=2.86e^-19= (8.365e^-24)v^2
=2.86e^-19          =v^2
   (8.365e^-24)         
           
v=584.72 m/s, 585 m/s (adjusted for sig figs)?         
« Last Edit: October 08, 2009, 03:26:02 PM by pistaciolow »

Offline pistaciolow

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Re: questions involving wavelengths and dissociation
« Reply #5 on: October 09, 2009, 08:53:53 AM »
Nevermind, I figured it out.

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