So...are you asking if there is something to be sure that there is lead in a solution? If so, you could use something like hydrochloric acid and a white precipitate would form that is PbCl
2 or PbCl
4. This would indicate the presence of lead, but I can't totally understand your question.
2HCl + Pb
PbCl
2 + H
2 (for Pb
2+)
4HCl + Pb
PbCl
4 + 2H
2 (for Pb
4+)
Hope this is what you were asking.