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Topic: Aqueous Reaction  (Read 3308 times)

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Offline larson

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Aqueous Reaction
« on: November 22, 2009, 11:42:39 PM »
Hey everyone! I have attempted this problem, but would like to know if I did it correctly.  Thanks!

An aqueous solution of silver nitrate (100.0 mL, 0.112 M silver nitrate) is mixed with an aqueous solution of potassium chloride (75.3 mL, 0.167 M potassium chloride), forming an insoluble precipitate,  After vacuum filtration, washing, and drying, 1.43 grams of the solid precipitate is recovered.

1. Write the chemical equation describing the reaction that occurs.  [Show all species as compounds (e.g. NaCl(aq)) rather than as ions (e.g. Na+(aq) + Cl-(aq)).

AgNO3(aq) + KCl(aq) = KNO3(aq) + AgCl(s)


2. Write the net ionic equation describing the reaction that occurs.

Ag+(aq) + Cl-(aq) = AgCl(s)


3. What is the theoretical yield (in grams) of the solid precipitate?

From the molarity equation... Moles = Molarity * Liters of Solution
Moles of silver nitrate = 0.112 M * 0.1 L
                             = 0.0112 moles AgNO3

Moles of potassium chloride = 0.167 M * 0.0753 L
                                     = 0.0126 moles KCl

Grams of AgCl = (0.0126 mol KCl)(1 mol AgCl / 1 mol KCl)(143 g AgCl / 1 mol AgCl)
                   = 1.80 g AgCl


4. What is the percent yield for this reaction?

Percent yield = (actual yield / theoretical yield) * 100
                  = (1.43 g AgCl / 1.80 g AgCl) * 100
                  = 74.4%

Is all of this correct, or no? If not, could somebody help me out?

Thanks,
Larson
« Last Edit: November 23, 2009, 12:13:21 AM by larson »

Offline Borek

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Re: Aqueous Reaction
« Reply #1 on: November 23, 2009, 03:35:28 AM »
Which substance (KCl or AgNO3) is a limiting reagent?
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Offline larson

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Re: Aqueous Reaction
« Reply #2 on: November 23, 2009, 04:26:15 AM »
Which substance (KCl or AgNO3) is a limiting reagent?

I believe AgNO3 is the limiting reagent.

Offline Borek

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Re: Aqueous Reaction
« Reply #3 on: November 23, 2009, 04:59:06 AM »
I believe AgNO3 is the limiting reagent.

Grams of AgCl = (0.0126 mol KCl)(1 mol AgCl / 1 mol KCl)(143 g AgCl / 1 mol AgCl)

So why you have calculated amount of product from moles of KCl?
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