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Topic: Degree of Unsaturation in 5-Cholesten-3-one  (Read 2684 times)

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Offline OrgoBorgo

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Degree of Unsaturation in 5-Cholesten-3-one
« on: November 27, 2009, 10:57:58 PM »
Hello again!
I just want to say I love this forum, it's very helpful and I'm glad I joined.
Now that I'm done kissing ass I have a question. :P

I've determined that 5-cholesten-3-one (C27H44O1 has a degree of unsaturation of 6.

DOU = [(#carbons x2 +2 +halogens) - (#observed hydrogens + halogens)] / 2 = 6

Degree of unsaturation accounts for the number of rings + db/tp etc..
However, I see 4 rings and 1 double bond. So am i supposed to account for the double bond to oxygen in order to provide the correct DOU of 6 instead of 5 (4 rings + 1 c=c)?

Thanks!

Steve, (OrgoBorgo).

Offline darkness1102

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Re: Degree of Unsaturation in 5-Cholesten-3-one
« Reply #1 on: November 28, 2009, 12:40:39 AM »
6 is correc, (27.2+2 -44)/2 =6. two duoble bonds ( C=O and C=C)  and 4 rings.

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