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Topic: Retro Diels Alder  (Read 4233 times)

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Offline Nemesisof99

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Retro Diels Alder
« on: November 30, 2009, 11:45:10 AM »
Are reverse Diels Alder reactions possible. If so, what are the reagents used to bring about the reverse reaction?

Offline stewie griffin

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Re: Retro Diels Alder
« Reply #1 on: November 30, 2009, 12:55:39 PM »
Retro-Diels-Alder reactions are indeed possible. Usually the "reagent" of choice is heat... other than that I haven't seen anything else. There usually needs to be some sort of driving force however, such as formation of simple stable molecules like N2 or acetone. In other words, you wouldn't propose to make a diene and an alkene from a retro-Diels-Alder.

Offline movies

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Re: Retro Diels Alder
« Reply #2 on: November 30, 2009, 01:14:04 PM »
We do it all the time when we crack the dimer of cyclopentadiene!

In principle anything that promotes the forward Diels–Alder reaction should also promote the retro-D–A.

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