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Topic: Aromaticity  (Read 2324 times)

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Offline sumedh

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Aromaticity
« on: December 03, 2009, 08:15:42 PM »
Why cyclopentadienyl anion ia aromatic in spite of presence of sp3 hybid carbon in the ring(negative charge bearing carbon which is a carbanion)?
Similarly in case of pyrrole nitrogen is sp3 hybrid still the ring is taken to aromatic why?
Do we assume them to be sp2 hybrid? why?
i am very confused

Offline nj_bartel

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Re: Aromaticity
« Reply #1 on: December 03, 2009, 08:26:01 PM »
If there is a lone pair present on what appears to be an sp3 atom, it generally hybridizes itself to sp2, positioning the lone pair in the p orbital to gain aromaticity.

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